Adsorption of aluminium by a latosol as affected by phosphate and glutamic acid     

Jie Wen Yang  Rong Fa Guo  Sheng Qi Chen 《Environmental Geology》2006,50(6):867-871

The effect of phosphate and glutamic acid on adsorption of aluminium onto a latosol was investigated as a function of pH and ligand concentrations through batch equilibrium experiments. The results showed that adsorption of aluminium by the soil was enhanced after addition of phosphate at low pH, and this promotive effect was gradually eliminated with the increase in pH. The positive effect of phosphate on aluminium adsorption onto latosol was attributed to phosphate-induced surface negative charge and formation of ternary surface complexes involving aluminium and phosphate. While using silica as adsorbent, the inactive surfaces for phosphate, promotion of adsorption of aluminium by phosphate was also found. Then it was proposed that additional aluminium might bind to the phosphate adsorbed onto the silica in the form of surface complexes silica–aluminium–phosphate again, and the mechanism might operate in the soil systems as well. Glutamic acid exhibited no influence on the adsorption of aluminium by the soil at low pH. After increasing the pH, adsorption of aluminium was inhibited especially with the highest addition of glutamic acid, probably owing to weak affinity of complexes between glutamic acid and aluminium to the soil.  相似文献   

Spectral Simulation and Conditioning to Local Continuity Trends in Geologic Modeling     

Tingting Yao  Craig Calvert  Tom Jones  Glen Bishop  Yuan Ma  Lincoln Foreman 《Mathematical Geology》2006,38(1):51-62

Spectral simulation has gained application in building geologic models due to the advantage of better honoring the spatial continuity of petrophysical properties, such as reservoir porosity and shale volume. Distinct from sequential simulation methods, spectral simulation is a global algorithm in the sense that a global density spectrum is calculated once and the inverse Fourier transform is performed on the Fourier coefficient also only once to generate a simulation realization. The generated realizations honor the spatial continuity structure globally over the whole field instead of only within a search neighborhood, as with sequential simulation algorithms. However, the disadvantage of global spectral simulation is that it traditionally cannot account for the local information such as the local continuity trends, which are often observed in reservoirs and hence are important to be accounted for in geologic models. This disadvantage has limited wider application of spectral simulation in building geologic models. In this paper, we present ways of conditioning geologic models to the relevant local information. To account for the local continuity trends, we first scale different frequency components of the original model with local-amplitude spectrum ratios that are specific to the local trend. The sum of these scaled frequency components renders a new model that displays the desired local continuity trend. The implementation details of this new method are discussed and examples are provided to illustrate the algorithm.  相似文献   

基于MPI的机群并行计算系统平台构建   总被引：4，自引：1，他引：4  

荣莹  曹俊兴 《物探化探计算技术》2005,27(1):89-91

在高性能计算机领域,机群并行系统已成为一种重要的系统结构。这里介绍了机群并行系统的特点和发展现状;给出了将PC机或工作站通过高速以太网连接,使用TCP/IP作为标准的通信协议,利用MPI作为分布式的并行计算软件环境,在Windows平台和Unix平台上搭建用户自己的PC机群系统的两种方法;还给出了MPI安装中需要注意的关键步骤。实践表明,PC机群系统具有高性能、高可用性和极高的性价比。  相似文献   

砂岩型铀矿勘查样品中铀的野外快速测定方法研究     

蔡金芳  张富平  张洁  王荣 《铀矿地质》2005,21(3):177-182,168

本文研究并建立了适合野外条件下快速测定砂岩型铀矿勘查试样中铀的分析方法———密闭酸溶试样、钒酸铵容量法测定铀。采用密闭增压酸溶样, 可使粒度小于0 25 mm的试样分解完全;小体积容量法提高了测定灵敏度。配合不同浓度的标准溶液可适应不同含量范围铀的测定。方法经标准物质和吐哈工区试样验证, 准确度和精度较高, 且操作简单, 适应性广, 具有实用和推广价值。  相似文献   

极谱测氟法在天然水和化妆品中的应用   总被引：1，自引：0，他引：1  

张蓉 《云南地质》2005,24(3):317-320

本文提出使用Zr4 ———钍试剂极谱法测定氟,具有灵敏、准确、快捷等特点。  相似文献   

中国大陆科学钻探（CCSD）主孔地区岩石圈热结构   总被引：11，自引：2，他引：11  

吴耀  金振民  欧新功  徐海军  王璐 《岩石学报》2005,21(2):439-450

岩石圈热结构是指地球内部热量在壳幔的配分比例、温度以及热导率和生热率等热学参数在岩石圈中的分布特征。岩石圈的热结构直接影响着岩石的物理性质和流变学性质,同时还控制了化学反应的类型和速度,从而制约着岩石圈的发展和演化。本文在前人CCSD主孔岩石主、微量元素研究基础上,利用Rybach生热率公式计算了钻孔岩石的放射性生热率,并结合岩石热导率的测定研究了CCSD主孔100-2000m岩石的热结构和主孔榴辉岩在不同退变质程度下生热率、热导率的变化:钻孔中岩石的平均生热率为0.95μWm-3,平均热导率为2.96mWm-1K-1。,其中片麻岩生热率高迭1.01-1.7μWm-3,热导率为2.76-2.96mWm-1K-1;基性超基性岩石生热率最低(<0.21μWm-3),热导率则高达3.20mWm-1K-1以上;新鲜榴辉岩生热率、热导率居中,分剐为0.16-0.44μWm-3和3.31-3.85mWm-1K-1。钻孔中榴辉岩生热率、热导率变化主要受岩性控制:从新鲜榴辉岩到完全退变榴辉岩,热导率总体上降低,但从强退变榴辉岩到完全退变榴辉岩,岩石热导率升高;而在此过程中岩石生热率总体上升高,仅当从中等退变质榴辉岩退变为强退变质榴辉岩时,岩石生热率出现降低趋势。在综合研究的基础上预测CCSD主孔5000m深度处温度为139℃,温度范围为131-151℃。根据区域深部地球物理探测成果对CCSD主孔地区岩石圈热结构进行了研究:上地壳底部温度为256℃,中地壳底部温度为492℃,Moho面温度为683℃,岩石圈底部温度为1185℃,来自地幔的热流为44.1mWm-2,对地表热流的贡献率为58%。研究结果表明,由岩石物理方法获得的CCSD主孔地区岩石圈地温曲线与石榴石-二辉橄榄岩包体推断的中国东部地温曲线十分吻合,本文从实验岩石物理学角度为CCSD主孔地区岩石圈热结构研究提供了重要约束  相似文献   

How Far Is Too Far? – A Statistical Approach to Context‐contingent Proximity Modeling     

Xiaobai Yao  Jean-Claude Thill 《Transactions in GIS》2005,9(2):157-178

Proximity is a fundamental concept in any comprehensive ontology of space ( Worboys 2001 ). The provision of a context‐contingent translation mechanism between linguistic proximity measures (e.g. “near”, “far”) and metric distance measures is an important topic in current GIS research. After a discussion of context factors that mediate the relationship between linguistic and metric distance measures, we present a statistical approach, Ordered Logit Regression, to the context‐contingent proximity modeling. The approach can predict proximity given the corresponding metric distance and context variables. An empirical case study with human subjects is carried out using this statistical approach. Interpretation and predictive accuracy of the empirical case study are discussed.  相似文献   

CAPPS多箱模式中光化学模式的嵌套与城市大气臭氧数值预报   总被引：3，自引：2，他引：3       下载免费PDF全文

张恺 徐大海朱蓉  陈军明 《应用气象学报》2005,16(1):1-12

为解决城市边界层中大气O₃浓度的预报问题，选用一种简明有效的光化学反应方案建立光化学模式, 并与大气平流扩散的箱格预报模型进行了嵌套，从而将大气化学过程引入到城市空气污染数值预报系统 (CAPPS) 中。同时，根据实际需要研究了VOC (Volatile Organic Compounds) 浓度及NO_x源排放量等参数缺测时，根据前期监测浓度采用遗传算法反演未知参数的具体方法。利用2001年9月8~17日在北京舞蹈学院监测的O₃、NO_x资料及相应的气象数据，用改进后的CAPPS模式进行了单箱预报试验。预报试验结果表明，嵌套后的模式对O₃浓度的变化具备一定的预报能力。  相似文献   

西北区东部一次暴雨的数值模拟试验   总被引：19，自引：23，他引：19  

王劲松  李耀辉  康凤琴  张华 《高原气象》2002,21(3):258-266

运用双向嵌套的中尺度数值预报模式MM5，对1998年7月上旬西北区东部一次暴雨过程进行了高分辨率数值模拟和敏感性试验。结果表明，该模式能较好地模拟这次暴雨过程，对这次暴雨过程相关的中尺度系统的发生发展也作出了较成功的模拟；大尺度及积云对流尺度的凝结潜热在降水过程中是一个主要因子，潜热释放将加热中高层大气，促使高层大气辐散，低层辐合，垂直运动加强，导致较大的降水；初始时刻不同地区低层大气水汽含量的多寡直接对本次暴雨产生影响，并为这次暴雨提供了水汽源；地面水汽和感热的垂直输送为暴雨的发生发展补充了能量。  相似文献   

新一代CAPPS系统的开发与推广应用     

朱蓉  徐大海 《中国气象科学研究院年报》2002,(1):36-37

2002年5月由中国气象局预测减灾司组织,中国气象科学研究院将城市空气质量数值预报系统(CAPPS)第二版发送给全国47个重点城市的气象部门,以取代CAPPS第一版在各城市的空气质量业务预报中应用.与此同时,中国气象科学研究院对47个城市的空气质量预报业务人员进行了培训.CAPPS2以Linux为工作平台在PC机上运行,污染气象预报场由MM5提供,T213资料和常规气象观测资料从MICAPS中获取,可以作48 h的城市污染预报,解决了预报时效问题.CAPPS2还提供各标准等压面上的位势高度、温度、相对湿度、风和降水等气象预报要素场,模式的中心点和网格距可以根据需要随意调整,各省市气象局可以在CAPPS基础上发展适用于本地区的中尺度气象预报、城市污染预报以及其他城市环境气象服务预报模式.  相似文献